Search results for "Hydrophobic coating"
showing 4 items of 4 documents
Surface functionalization of metal-organic frameworks for improved moisture resistance
2018
Metal-organic frameworks (MOFs) are a class of porous inorganic materials with promising properties in gas storage and separation, catalysis and sensing. However, the main issue limiting their applicability is their poor stability in humid conditions. The common methods to overcome this problem involve the formation of strong metal-linker bonds by using highly charged metals, which is limited to a number of structures, the introduction of alkylic groups to the framework by post-synthetic modification (PSM) or chemical vapour deposition (CVD) to enhance overall hydrophobicity of the framework. These last two usually provoke a drastic reduction of the porosity of the material. These strategie…
One-step electrodeposition of superhydrophobic coating on 316L stainless steel
2021
Superhydrophobic coatings were fabricated through a one-step electrochemical process onto the surface of 316L stainless steel samples. The presence of hierarchical structures at micro/nanoscale and manganese stearate into the coatings gave superhydrophobicity to the coating, with contact angle of ~160°, and self-cleaning ability. Corrosion resistance of 316L samples was also assessed also after the electrodeposition process through Electrochemical Impedance Spectra recorded in an aqueous solution mimicking seawater condition.
Surface Functionalization of Metal–Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance
2021
Robust catechol coatings for enhanced moisture tolerance were produced in one step by direct reaction of Hong Kong University of Science and Technology (HKUST) with synthetic catechols. We ascribe the rapid formation of homogeneous coatings around the metal–organic framework particles to the biomimetic catalytic activity of Cu(II) dimers in the external surface of the crystals. Use of fluorinated catechols results in hydrophobic, permeable coatings that protect HKUST from water degradation while retaining close to 100% of its original sorption capacity.
Double Step Electrochemical Process for the Deposition of Superhydrophobic Coatings for Enhanced Corrosion Resistance
2021
Superhydrophobic surface on anodized AA5083 sample was obtained by an electrochemical process. Scanning Electron Microscopy and Fourier Transform Infrared Spectroscopy analyses revealed the hierarchical structure of the coating and the presence of manganese stearate. These features were crucial for the coating superhydrophobicity, demonstrated by a measured contact angle of ~ 163° and its self-cleaning ability. Electrochemical characterization in an aqueous solution mimicking seawater proved an enhanced corrosion resistance due to the superhydrophobic coating with respect to anodized AA5083 sample that also lasted after 20 immersion days in Cl- containing electrolyte.